Correlation of Oxygen Storage Capacity and Structural Distortion …
Oxygen storage/release (OSC) capacity is an important feature common to all three-way catalysts to combat harmful exhaust emissions. To understand the …
Oxygen storage/release (OSC) capacity is an important feature common to all three-way catalysts to combat harmful exhaust emissions. To understand the …
Oxygen storage/release (OSC) capacity is an important feature common to all three-way catalysts to combat harmful exhaust emissions. To understand the …
X-ray diffraction (XRD), X-photon spectra (XPS), high-resolution transmission electronic microscopy (HRTEM) and H2 temperature programmed reduction (TPR) were carried out …
18 · Pt/CePr/Al 2 O 3 has the highest oxygen storage/release capacity, which promotes the occurrence of carbon removal mechanism on metal surface. The …
Abstract Oxygen storage and release is a foundational part of many key pathways in heterogeneous catalysis, such as the Mars-van Krevelen mechanism. However, direct measurement of oxygen storage capacity (OSC) is …
The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances. Metal–organic frameworks (MOFs) have attracted the attention of the scientific community in the last fifteen years, 1 giving rise to an extraordinary amount …
Portable liquid cylinder: A vacuum insulated cryogenic container used for the storage of liquefied gases having a maximum allowable working pressure of greater than 0.5 bar and the capacity normally not exceeding 500 litres. Primary source ofsystem
CeO 2 is widely used as a catalyst support component due to its redox property of oxygen storage and release. This unique feature, which is usually referred to …
T,M., Büchs, J. 2014. Liquid films on shake flask walls explain increasing maximum oxygen transfer capacities with elevating viscosity. Biotechnol. Bioeng. 111(2): 295-308. In summary, the OTR max defines the capacity for oxygen transfer in a system and is
Oxygen storage capacity and thermal stability of the CuMnO 2 –CeO 2 composite system X. Huang, C. Ni, G. Zhao and J. T. S. Irvine, J. Mater em. A, 2015, 3, 12958 DOI: 10.1039/C5TA01361E This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. ...
Johnson Matthey''s international journal of research exploring science and technology in industrial applications
Oxygen storage capacity measurements of three-way catalysts under transient conditions Claude Descormea,∗, Rachid Tahaa, Najat Mouaddib-Moralb, Daniel Dupreza a Laboratoire de Catalyse en Chimie Organique (LACCO) — UMR CNRS 6503, Université de Poitiers,
Co-Mn-Mg-Al oxides were synthesized using auto-combustion and co-precipitation techniques. Constant ratios were maintained with (Co + Mn + Mg)/Al equal to 3.0, (Co + Mn)/Mg equal to …
• A cryogenic liquid oxygen tank which can be installed in a vertical or horizontal position. • Capacity typically ranges from 500 to 25,000 liters of liquid oxygen storage for health facility use. Larger capacity units can be custom built as needed. • The maximum
We suggest that the convergent evolution of high myoglobin net surface charge in mammalian divers increases intermolecular electrostatic repulsion, permitting higher muscle oxygen storage capacities without potentially deleterious self-association of …
Doping CeO2 with Y cations was achieved in this study using three strategies: doping only during the hydrothermal process (H-Y-doped CeO2), doping only during the impregnation process (I-Y-doped …
The oxygen storage capacity, or the reducible oxygen, was determined by temperature programmed reduction (TPR) in the TGA, with the temperature increased from 120 C to 950 C at a heating rate of 5 C min −1 in 5.0 vol% …
The largest oxygen content δ reached 1.054, 1.188 and 1.070 for Y0.95Ti0.05BaCo4O7+δ, DyBaCo4O7+δ, Y0.2Ti0.05Dy0 ... δ ≈ 1.2, corresponding to the oxygen storage capacity of 1225 μmol O 2 g −1 is larger than the theoretical value (870 μmol O 2 g −1 2 2 ...
Abstract Ceria–zirconia solid solution is a very important material in three-way catalysts for automotive emission control. High oxygen storage capacity (OSC) and thermally stable Ce 0.5 Zr 0.5 O 2 was prepared by a modified complexing–coprecipitation (CC) method, and its surface area reached 44 m 2 g −1 after calcination at 1100 C for 6 h. . Based on the …
In this work, a correlation between ceria loading (0, 2, 5, 10, 20, 50 wt%) in Pt/Al2O3-CeO2 catalysts with the catalytic activity of 1-butanol and toluene oxidation is presented. The materials were characterized by TPR, CO chemisorption and TEM; additionally, the capacity to store/release oxygen was determined with the OBC …
Oxygen storage/release (OSC) capacity is an important feature common to all three-way catalysts to combat harmful exhaust emissions. To understand the mechanism of improved OSC for doped CeO2, we undertook the structural investigation by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), H2-TPR (temperature …
Because storing/releasing oxygen proceeds from the catalyst front to the backside, the maximum RF-sensitivity must be expected when the oxygen storage process occurs in the middle of the catalyst. As explained previously, Figure 5 c,d show the relative change of the inverse (unloaded) quality factor depending on the TWC oxygen …
Search for high-capacity oxygen storage materials by materials informatics† Nobuko Ohba, *a Takuro Yokoya,b Seiji Kajitaa and Kensuke Takechi a Oxygen storage materials (OSMs), such as pyrochlore type CeO 2–ZrO 2 (p-CZ), are used as a catalyst support for
Oxygen storage materials (OSMs), such as pyrochlore type CeO 2–ZrO 2 (p-CZ), are used as a catalyst support for three-way catalysts in automotive emission control systems. They have oxygen storage capacity (OSC), which is the ability to release and store
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